材料期刊网

INFLUENCE OF ALLOYING ELEMENTS(Nb,Mo,V) ON MICROSTRUCTURE OF Ti_3Al BASE ALLOYS

SONG Dan , DING Jinjun , WANG Yandong(Analysis and Testing Center , Northeastern University , Shenyang 110006 , China)

金属学报(英文版)

The microstructures of Ti-14Al-21Nb and Ti-14Al-20Nb-2Mo-3.2V(wt%) alloys have been investikated by transmission electron microscopy(TEM).The phase constitution and the orientation relationship between α2and βwere identified by means of the selected area diffraction and the micro-diffraction techniques.Results show that,compared to Ti-14Al-21Nb,the alloying elements Mo and V can greatly increase the fraction of β phase and improve significantly the microstructures of Ti-14Al-20Nb-2Mo-3.2V.The ordered B2 structure is also evident in the residual βgrains of the latter alloy.

关键词: :microstructure , null , null , null

Microstructures and Mechanical Properties of FeMn(Al, Si) TRIP/TWIP Steels

DING Hua , TANG ZhengYou , LI Wei , WANG Mei , SONG Dan

钢铁研究学报(英文版)

The mechanical properties and microstructure of two low carbon high manganese steels with 238% (No1) and 33% (No2) (mass percent) of manganese were investigated. The results showed that No1 steel possesses high strength and high plasticity, and No2 steel has a relatively high strength and extraordinary plasticity. The No1 steel exhibits both TRIP (transformation induced plasticity) and TWIP (twin induced plasticity) effects during the deformation; while only TWIP effect appeared under the same deformation condition for No.2 steel. The comparison between the microstructures and mechanical properties of two steels was made, and the strengthening mechanisms were also analyzed.

关键词: manganese;TRIP;TWIP;microstructure;mechanical property

Correctness and completeness of the theory of bio-energy transport Reply to the comments on "The theory of bio-energy transport in the protein molecules and its properties"

Physics of Life Reviews

Commentaries by Philip W.T. Pong, Nongyue He, S.D. Liang, Tao Song, Yuri Gaididei and Sergey Volkov and Alexander Y. Grosberg on my review article (Pang, 2011 [1]) are answered. The validity of Davydov's mechanism of bio-energy transport, the completeness of theory, outstanding problems, the normalization and validity of wave function of the system in Pang' model as well as other related problems are elucidated in detail. (C) 2011 Elsevier B.V. All rights reserved.

关键词: biological temperature;3 channels;soliton;model

磷在12Cr1MoV钢中非平衡晶界偏聚动力学的实验研究

李莉 , 李庆芬 , 郑磊 , 徐庭栋 , 杜善义

钢铁研究学报

以工业用12Cr1MoV钢为研究对象,通过俄歇电子能谱分析方法(AES),对磷在恒温过程中的非平衡晶界偏聚浓度进行了测定.获得的磷在钢中的非平衡晶界偏聚动力学曲线直接验证了非平衡晶界偏聚动力学理论中的Xu-Song模型.

关键词: 晶界偏聚 , 临界时间 , 扩散 , 钢

RELATIONSHIP BETWEEN THE EXISTENCE OF MICROBES AND EARLY CORROSION BEHAVIOR OF MILD STEEL IN FRESH WATERS

Fresenius Environmental Bulletin

The relationship between existence of microbes and early corrosion behavior of mild steel in fresh waters was studied using immersion tests, electrochemical measurements and surface analysis techniques. In the field immersion test at Dan Jiangkou reservoir in China, mild steel had less corrosion weight loss in the upper layer of water, where more microbes existed. The accumulation of microbes on the surface of coupons was thought to slow down the corrosion rate by restricting the oxygen diffusion and other factors. This hypothesis was confirmed by the electrochemical measurements and immersion test in natural freshwater. The results of the Scanning Electron Microscopy (SEM) and Fourier Transform Infra-red (FT-IR) spectra further confirmed that the existence of microbes could affect the formation of the corrosion products. Furthermore, the surface film formed in microbes-contained freshwater was thicker and with more complex corrosion products.

关键词: Corrosion;freshwater;eutrophication;microbes;mild steel;microbiologically influenced corrosion;biocorrosion

镁合金表面功能纳米薄膜的制备

衷诚武 , 叶奇 , 简炜炜

钛工业进展 doi:10.3969/j.issn.1009-9964.2007.02.006

通过有机镀膜技术,对镁合金表面进行改性.对有机镀膜处理后的镁合金表面的接触角,表面自由能进行了测定.研究了不同有机镀液,在恒电流作用下,有机镀膜时间对镁合金表面性能的影响.结果表明,经过TTN溶液有机镀膜后,镁合金板表现出亲水性,其表面能比未处理镁合金板的表面自由能要高;而经过DHN和DAN溶液有机镀膜后,镁合金板表现出良好的疏水性,其表面能比未处理镁合金板的表面自由能要低,在二者中DHN处理后的疏水效果最好.实现了对镁合金表面疏水、亲水表面改性,能够很好的扩大镁合金在工业中的应用领域.

关键词: 镁合金 , 有机镀膜 , 亲水薄膜 , 疏水薄膜

2,6-二(2′-咪唑啉-2′-基)吡啶合铬(Ⅲ)的合成及其与DNA的相互作用

张金艳 , 肖小明 , 蒋艳 , 谭年元

应用化学 doi:10.3724/SP.J.1095.2010.90729

在微波辐射和无催化剂条件下,由吡啶2,6-二甲酸与乙二胺反应合成了2,6-二(2′-咪唑啉-2′-基)吡啶(L),采用常规加热法合成其配合物[CrL2][NO3]3. 用核磁共振、红外光谱、元素分析、热重分析和摩尔电导率测试技术对其进行表征分析. 通过紫外吸收光谱和黏度测试,分别考察了配体及配合物与DNA的键合常数及其作用方式. 结果表明,配体L以氢键和沟面作用方式与DAN键合,而配合物以氢键和静电作用模式与DNA键合. 密度泛函理论(DFT)计算结果较好的解释了L及[CrL2]3+与DNA的相互作用模式.

关键词: 二(咪唑啉基)吡啶 , 铬配合物 , DNA , 微波辐射 , DFT

铝表面三嗪硫醇高分子纳米薄膜的电化学制备

王芳 , 王茜 , 罗和义 , 王景刚 , 许娟

材料科学与工程学报

通过电化学的方法,利用一种自设计合成的6-N,N-烯丙基氨基-1,3,5-三嗪-2,4-硫醇(简称DAN)在金属铝表面制备高分子纳米薄膜.通过反射吸收红外光谱(RA-IR)对此三嗪硫醇的高分子纳米薄膜(PDA)的化学结构进行了确定.同时对于铝表面形成的PDA薄膜进行了接触角、膜厚和膜重测定.测定结果显示:只有在亚硝酸钠作为支持电解质的条件下,在铝的表面形成了三嗪硫醇高分子纳米薄膜;并且形成的三嗪硫醇高分子纳米薄膜的膜厚及重量与电解时间和电位成正比.通过原子力显微镜对不同电解电位条件下形成的薄膜表面形态和表面粗糙程度进行了评价,表明通过恒电位法使用较高的电解电位在铝表面获得了均匀致密的PDA薄膜,为在铝表面制备有机介电薄膜提供了研究基础.

关键词: 金属铝 , 6-N,N-二烯丙基氨基-1,3,5-三嗪-2,4-硫醇(DAN) , 高分子 , 纳米薄膜 , 电化学